Crystal structure of (μ-4-hydroxybenzenethiolato-κ2 S:S)bis(μ-phenylmethanethiolato-κ2 S:S)bis[(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] tetrafluoridoborate
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چکیده
The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H⋯F hydrogen bond and several weak C-H⋯F inter-actions. This is the first example of an X-ray analysis of a mixed dinuclear tri-thiol-ate arene ruthenium(II) complex.
منابع مشابه
Crystal structure of bis[μ-(4-methoxyphenyl)methanethiolato-κ2 S:S]bis[chlorido(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] chloroform disolvate
The mol-ecular structure of the title complex, [Ru2(C8H9OS)2Cl2(C10H14)2]·2CHCl3 or (p-MeC6H4Pr (i) )2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3, shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth-oxy-α-toluene-thiol-ato [(4-meth-oxy-phen-yl)methane-thiol-ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environmen...
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